No free-standing nanotubes released in tyre tread wear – OCSiAl

A tyre with a tread enhanced with single wall carbon nanotubes was exposed to accelerated wear and handling simulation tests by Akron Rubber Development Laboratory. Analysis of captured airborne particles showed no free-standing nanotubes, according to Luxembourg-based OCSiAl, which produces carbon nanotubes.

The finding that no aerosolized nanotubes were released in the air during simulation of the life cycle of tyres “unlocks the door to mass use of single wall carbon nanotubes that have tyre industry-acknowledged benefits”, according to OCSiAl. Proposed improvements include: “safety and durability, and reduced energy consumption and vehicle CO2 emissions”.

Single wall carbon nanotubes, also known as graphene nanotubes, offer unique benefits in comparison to standard tyre additives, such as silica and carbon black, leading to a growing number of projects for developing safer and more eco-friendly tyres. Possible release of nanoparticles into the air was of interest for the tyre industry, which is heavily focused on environmental aspects.

The test was performed by ARDL (Akron Rubber Development Laboratory), at a Calspan facility in Cleveland, OH.

“We have introduced Tuball nanotubes produced by OCSiAl into tread to check the probability of nanoparticles exposure, as this tire component experiences the main wear during the car’s motion. An independent laboratory captured any possible aerosol released and applied a specific quantification method relying on Raman spectroscopy for the detection of airborne particles. Only rubber particles with nanotubes embedded into the matrix were discovered. No free-standing TUBALL nanotubes were observed,” said Gunther Van Kerckhove, H&S Lead Manager at OCSiAl.

The performed test once again verifies the results shown by VITO, a leading independent European research and technology organization, in 2017 during abrader tests on single wall carbon nanotube-enhanced epoxy, polyethylene, and elastomer samples. Taber abrading tests revealed no free-standing or protruding nanotubes in those tests. The reason lies in single wall carbon nanotubes’ bonding strength and their unique morphology: ultra-flexible with a 3000:1 length-to-diameter ratio.

“Exposure monitoring studies with material samples are not sufficient for the tyre industry. We wanted to check the exposure of a real tyre with nanotubes during wear similar road conditions – to check potential impact to human health and the environment. After confirming that no single wall carbon nanotubes are expelled during tyre usage, the next step will be to verify that there is no exposure during recycling of a tyre either,” said Jean-Nicolas Helt, Development and Support Leader for Elastomers at OCSiAl.